ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Synergistic Static and Dynamic Interfacial Regulation Toward Robust Zinc Batteries.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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12 authors.
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Abstract
Aqueous zinc (Zn) metal batteries (AZMBs) are promising for sustainable energy storage, yet their development is severely compromised by the interfacial instability arising from a water-rich and disordered electric double layer (EDL). Herein, we establish a rational screening strategy that combines density functional theory with molecular dynamics simulations to identify cationic regulators (both organic and inorganic) capable of reshaping the EDL structure through optimized interfacial affinity and transport kinetics. The results reveal that 1-ethyl-3-methylimidazolium exhibits strong interfacial affinity, which enables the formation of a hydrophobic shielding layer that suppresses parasitic reactions, demonstrating a "static passivation" effect. In contrast, sodium ion, as electric field-responsive species, provides "dynamic regulation" by homogenizing Zn
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