ArticleAngewandte Chemie (International ed. in English)2026
Azole γ-Peptides Helix Switching via Heterocycle Substitutions.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Precise control of peptide backbone folding through non-covalent interactions remains a major challenge in foldamer design. In this work, we demonstrate that heteroatom substitutions program conformational switching in azole γ-peptides by tuning intrinsic stereoelectronic effects within heterocyclic γ-amino acids. Conformationally constrained thiazole- and oxazole-based γ-amino acids were designed to adopt conformations driven by either a C
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