ArticleMacromolecular rapid communications2026
Influence of Adding Cyclodextrin Derivatives on the Mechanical and Thermal Properties of Glassy Polymers.
Article in Macromolecular rapid communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The use of naturally derived materials for reinforcing and modifying polymer materials contributes to the development of sustainable polymer materials and reduces petroleum consumption. Cyclodextrin (CD) derivatives are promising naturally derived additives for reinforcing and modifying polymer materials. In this study, we investigated the influence of triacetylated γ-cyclodextrin (TAcγCD) addition and pseudorotaxane formation on the mechanical and thermal properties of poly(methyl methacrylate) (PMMA) to elucidate the reinforcement mechanism. The incorporated TAcγCD primarily reinforced PMMA by acting as a rigid filler, with the reinforcement behavior following the Guth-Gold equation. Notably, pseudorotaxane formation slightly increased the Young's modulus compared to the value predicted by the equation, suggesting that pseudorotaxane formation may provide a modest additional contribution beyond conventional filler reinforcement. In addition, the glass transition temperature (T
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