Evidence map›Paper›PMID 42463706›Full record

ArticleNature communications2026

Structural and spectroscopic characterization of a Tb(IV) polyoxometalate.

Primadi J Subintoro, Brett Lottes, Felipe A Pereiro, Nolwenn Mahieu, Alexander M Brown, S Genevieve Duggan, Monica S Mullis, Aldo M Jordan, Cassandra Gates, Samuel M Greer and 9 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

19 authors.

Primadi J SubintoroDepartment of Chemistry, University of Iowa, Iowa City, IA, USA.
Brett LottesDepartment of Chemistry, University of Iowa, Iowa City, IA, USA.
Felipe A PereiroChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA.
Nolwenn MahieuChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.
Alexander M BrownChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.ORCID http://orcid.org/0000-0002-1497-213X
S Genevieve DugganDepartment of Chemistry, University of Iowa, Iowa City, IA, USA.
Monica S MullisChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA.
Aldo M JordanChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA.
Cassandra GatesChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA.
Samuel M GreerChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA.ORCID http://orcid.org/0000-0001-8225-3252
Joshua J WoodsChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.ORCID http://orcid.org/0000-0002-6213-4093
Rebecca J AbergelChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.ORCID http://orcid.org/0000-0002-3906-8761
Jenifer C ShaferDepartment of Chemistry, Colorado School of Mines, Golden, CO, USA.
Daniel K UnruhOffice of the Vice President for Research, University of Iowa, Iowa City, IA, USA.ORCID http://orcid.org/0000-0002-2594-5786
Pere MiróDepartment of Chemistry, University of Iowa, Iowa City, IA, USA. pere-miro@uiowa.edu.
Benjamin W SteinChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA. bstein@lanl.gov.ORCID http://orcid.org/0000-0002-0366-5476
Jennifer N WackerChemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA. jwacker@lbl.gov.ORCID http://orcid.org/0000-0001-5411-1986
Stosh A KozimorChemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA. stosh@lanl.gov.ORCID http://orcid.org/0000-0001-7387-0507
Korey P CarterDepartment of Chemistry, University of Iowa, Iowa City, IA, USA. korey-carter@uiowa.edu.ORCID http://orcid.org/0000-0003-4191-0740

Funding

National Science Foundation (NSF) CHE-1828117U.S. Department of Energy (DOE) 2020LANLE372U.S. Department of Energy (DOE) DE-AC02-05CH11231U.S. Department of Energy (DOE) DE-AC02-76SF00515U.S. Department of Energy (DOE) DE-SC0014664U.S. Department of Energy (DOE) DE-SC0020189U.S. Department of Energy (DOE) DE-SC-0023477U.S. Department of Energy (DOE) DE-SC0024035
6 · The paper itself

Abstract

There has been a renaissance in high valent lanthanide chemistry, which has resulted in the first examples of tetravalent praseodymium (Pr) and terbium (Tb) in molecular systems. These feats have been achieved with tailored ligands that facilitate tetravalent lanthanide stability in non-aqueous conditions. The next step in realizing the potential of high valent lanthanide chemistry is moving towards complexes that are stable in ambient and aqueous conditions. In this investigation, we advance this paradigm by obtaining definitive evidence of Tb(IV) in a molecular system under aqueous conditions utilizing the lacunary Wells-Dawson polyoxometalate, K

Identifiers

PMID42463706
PMCPMC13490611

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.