ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Color-Tunable Broadband Chiral Copper(I) Halides Scintillators for High-Resolution X-Ray Polarization Imaging.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Utilizing the circularly polarized luminescence (CPL) of scintillators offers a distinct advantage for X-ray imaging, as it significantly reduces optical crosstalk. Herein, we propose an effective strategy of crown ether-assisted self-assembly combined with halogen regulation to construct two novel pairs of isostructural chiral copper(I) halide clusters: R/S-Br and R/S-I. Under X-ray or UV light excitation, R/S-Br exhibits red broadband emission with a photoluminescence quantum yield (PLQY) of 77.0%, time-resolved PL (TRPL) decay time of 35.8 µs, and scintillation light yield (LY) of 5819 photons/MeV. In contrast, R/S-I displays yellow-green broadband emission with a near-unity PLQY, TRPL decay time of 2.86 µs, and a high LY of 14389 photons/MeV. The CPL asymmetry factor of S-Br and R-I is 1.23 × 10
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