ArticleChemical science2026
Asymmetric Chichibabin diradicaloids: synthesis
Zenghui Li, Jing Wang, Changyuan Xu, Tian Han, Jie Xiong, Honghong Gong, Zhicheng Zhang, Bin Rao
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In one paragraphArticle in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Zenghui LiSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.
Jing WangSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.
Changyuan XuSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.
Tian HanSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.ORCID https://orcid.org/0000-0002-8753-7999 Jie XiongSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.
Honghong GongSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.
Zhicheng ZhangSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.ORCID https://orcid.org/0000-0003-1871-117X Bin RaoSchool of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University Xi'an China robin616@mail.xjtu.edu.cn.ORCID https://orcid.org/0000-0002-3229-5558 Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
Since the discovery of Chichibabin hydrocarbon in 1907, its scaffold has been instrumental in designing diverse open-shell materials. However, synthetic efforts have yielded almost exclusively symmetric diradicaloids; asymmetric variants with two distinct radical centers remain elusive due to the challenge of forming two different radicals simultaneously. Herein, starting from SOMO-HOMO inversion radicals (2a and 2b) bearing polychlorinated trityl and triarylamine scaffolds, asymmetric Chichibabin diradicaloids (2a
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PMID42459920
PMCPMC13372135
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