Evidence map›Paper›PMID 42454734›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Adsorption Energy Difference-Driven Synthesis of Perovskite Single Crystals With Tailored Exposed Facets.

Yingjie Zhao, Jinjin Zhao, Xinzhang Lin, Jingyuan Zhang, Mengru Zhang, Meng Yuan, Kaixin Dong, Xiangxiang Yang, Ke He, Yuyan Zhao and 8 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

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5 · Who and what money

Authors and funding

18 authors.

Yingjie ZhaoCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.ORCID https://orcid.org/0000-0003-3433-5039
Jinjin ZhaoShanxi Key Laboratory of Microstructure Electromagnetic Functional Materials, Shanxi Datong University, Datong, People's Republic of China.ORCID https://orcid.org/0009-0008-0698-799X
Xinzhang LinDepartment of Heterogeneous Catalysis, Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany.
Jingyuan ZhangShanxi Key Laboratory of Microstructure Electromagnetic Functional Materials, Shanxi Datong University, Datong, People's Republic of China.ORCID https://orcid.org/0009-0009-6242-2106
Mengru ZhangCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.
Meng YuanState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry and International Center of Future Science, Jilin University, Changchun, People's Republic of China.
Kaixin DongCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.
Xiangxiang YangShanxi Key Laboratory of Microstructure Electromagnetic Functional Materials, Shanxi Datong University, Datong, People's Republic of China.
Ke HeKey Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, People's Republic of China.
Yuyan ZhaoState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry and International Center of Future Science, Jilin University, Changchun, People's Republic of China.
Jianpeng MaSuzhou Institute for Advanced Research, University of Science and Technology of China, Suzhou, People's Republic of China.
Jiawang ZouSuzhou Institute for Advanced Research, University of Science and Technology of China, Suzhou, People's Republic of China.
Junjie LiuCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.
Dan LiCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.
Xiao WeiKey Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, People's Republic of China.
Lei JiangState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry and International Center of Future Science, Jilin University, Changchun, People's Republic of China.
Yuchen WuKey Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, People's Republic of China.ORCID https://orcid.org/0000-0002-3451-7062
Yanlin SongCollege of Chemistry and Pingyuan Laboratory, Zhengzhou University, Zhengzhou, People's Republic of China.ORCID https://orcid.org/0000-0002-0267-3917

Funding

Fundamental Research Program of Shanxi Province 202303021222213National Natural Science Foundation of China 22305146National Natural Science Foundation of China 22575228National Natural Science Foundation of China 52303257National Natural Science Foundation of China T2394480National Natural Science Foundation of China T2394484National Natural Science Foundation of China T2425026Natural Science Foundation of Henan 262300421198
6 · The paper itself

Abstract

The precise synthesis of perovskite single crystals with tailored exposed facets is crucial for enhancing the performance of optoelectronic materials. However, the controlled preparation of perovskite single-crystal with different exposed facets is challenging, because perovskite tends to grow thermodynamically stable crystal facets, hindering systematic investigations of facet-dependent optoelectronic properties. Here, we first realized the synthesis of facet-specific perovskite single crystals via a coordination competition strategy mediated by the crystal-habit modifier, achieving morphological manipulation from cubic (100) to dodecahedral (110) facet-dominant structures. The formation mechanism of non-thermodynamic (110) facets originates from strong coordination between the crystal-habit modifier and (110) facets, which selectively inhibits (110) facet growth and finally produces a (110) facet-dominated single crystal. Optoelectronic characterization reveals distinct facet-dependent properties, with (110) facets exhibiting higher defect density compared to (100) facets. Performance evaluations demonstrate that lower defect densities in (100) facets enhance photodetector performance, while the elevated defect densities in (110) facets improve photocatalytic performance. This study establishes a new paradigm for tailoring perovskite crystal facets and provides fundamental insights for designing high-performance optoelectronic materials.

Indexed as

competitive coordinationcrystal facetscrystallizationphotocatalysisphotodetector

Identifiers

PMID42454734
PMCPMC13573148

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.