ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Ni-Induced Low-Valence Tungsten Oxide for Highly Selective and Stable Glycerol Electro-Oxidation to Formic Acid.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Electrocatalytic upgrading of renewable biomass-derived glycerol represents a sustainable method to produce value-added chemicals, but the complex reaction network of key intermediates during the glycerol oxidation poses challenges to product selectivity. Herein, we report a nickel-doped tungsten oxide catalyst grown on nickel foam (Ni-WOx/NF) for the highly selective electrooxidation of glycerol to formic acid (FA). This optimized catalyst achieves an FA Faraday efficiency (FE) of 95.1% and operates stably for over 18 h, outperforming conventional non-precious metal catalysts. Mechanistic understanding revealed that nickel doping effectively modulates the valence states of tungsten, increasing the proportion of low-valent W
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