ArticlePolymers2026
Preparation of an Ester-Based Polymeric Hydration Temperature Rise Inhibitor and Its Action Mechanism on Cement Hydration.
Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
To address the thermal cracking induced by concentrated heat release during early cement hydration, a novel Ester-based Polymeric Hydration Temperature Rise Inhibitor (ETRI) was designed and synthesized in this study based on the slow hydrolysis property of ester functional groups. After its incorporation into cementitious materials, the influence of ETRI on the hydration kinetics and the microstructure of hardened paste was systematically investigated. The results demonstrate that ETRI effectively regulates the heat release profile of cement hydration by prolonging the induction period. Specifically, at a dosage of 1.5%, ETRI reduces the peak heat release rate by 70.32% and the 72 h cumulative heat release by 70.82%. Mechanistic investigation reveals that ETRI undergoes slow hydrolysis in the alkaline environment to generate carboxyl groups that complex with Ca
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