ArticleAdvanced materials (Deerfield Beach, Fla.)2026
An Efficient and Durable Low-Iridium Catalyst Enabled by a Potential-Triggered Dual-Pathway Mechanism for Acidic Water Oxidation.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Addressing the activity-durability trade-off of low-iridium anode catalysts remains a key challenge for acidic oxygen evolution reaction (OER) in proton exchange membrane water electrolysis (PEMWE). Herein, we develop a three-dimensional ordered macroporous (3DOM) Cr─Ir solid solution oxide to regulate intersite oxygen intermediate reactivity for efficient and durable acidic water oxidation. Solid solution formation, together with the ordered macroporous architecture, creates electronically and geometrically coupled Cr─Ir dual sites that enable a potential-triggered coupling between the conventional adsorption evolution mechanism (AEM) and the oxide pathway mechanism (OPM). Beyond the AEM pathway involving *OOH intermediates at Ir sites, anodic polarization activates surface Cr─OH species into Cr─O moieties that cooperate with adjacent Ir─O species to promote intersite O─O coupling, thereby preserving the structural robustness associated with AEM while harnessing the activity advantage of OPM. As a result, Cr
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