ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Polarity-Engineered, Tribo-Positive Imidazolium-Mediated Crosslinked 6FDA-Durene Films for Triboelectric Nanogenerator.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Polarity-Engineered, Tribo-Positive Imidazolium-Mediated Crosslinked 6FDA-Durene Films for Triboelectric Nanogenerator.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
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Authors and funding
9 authors.
Funding
Abstract
Expanding the library of polarity-engineered polymers is essential for enhancing performance and designing the flexibility of triboelectric nanogenerators (TENGs). Herein, we report a polyimide (PI) film derived from an imidazolium-mediated cross-linked 6FDA-durene polymer, with bromine anions as counterions, enabling surface polarity modulation and improved charge transfer. XPS and FT-IR analyses confirm the formation of imidazolium-mediated crosslinks in the 6FDA-durene polyimide, verifying the successful incorporation of ionic liquid groups into the polymer structure. Density-functional theory (DFT) calculations reveal that imidazolium crosslinking shifts the HOMO upward by 1 eV, lowering the electron-transfer barrier and switching the triboelectric polarity from negative to positive. The fabricated TENG achieves a power density of 85.67 mW/m
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