ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Direct Visualization and Regulation of Interfacial Ion Concentration Layer at Zinc Metal Interfaces via an Ion-Buffering Artificial Solid Electrolyte Interphase.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Direct experimental visualization of the electrical double layer (EDL) and its associated layer formation at metal-electrolyte interfaces remains challenging yet is essential for understanding interfacial instability in zinc metal anodes. Herein, we engineer a PEO/PIM-1 hybrid polymer (PIP) as an artificial solid-electrolyte interphase (SEI) that replaces field-driven interfacial ion accumulation with confined ion buffering, thereby suppressing EDL amplification and chaotic interfacial dynamics. Liquid-phase atomic force microscopy (AFM) measurements demonstrate the elimination of voltage-dependent force amplification upon PIP modification, evidencing effective decoupling of electric-field-induced ion crowding at the Zn surface. In situ Raman spectroscopy, electrochemical analysis, and molecular dynamics simulations further reveal reduced interfacial water activity, regulated ion distribution, and homogeneous Zn stripping and deposition. PIP significantly enhances anode stability, enabling Zn|Zn symmetric cells to cycle for 2700 h and delivering a Coulombic efficiency of 98.6% in Zn|Ti cells. When coupled with I
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