ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Resolving the Strength-Modulus-Elasticity Tradeoff in Elastomers Using Dual Phase-Separated Nanodomains.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Achieving elastomers that simultaneously combine ultrahigh strength, high modulus, and excellent elasticity remains a longstanding challenge because these properties are intrinsically conflicting. Here, we report a dual phase-separated nanodomain strategy that resolves this trade-off by transforming reversible cross-links into spatially confined reinforcing nanodomains. Elastomers are fabricated via copolymerization of rigid aromatic polyurea segments with flexible poly(urethane-urea) chains containing acylsemicarbazide moieties. The resulting elastomers exhibit an exceptional combination of mechanical properties, including tensile strength of 104.6 MPa, Young's modulus of 43.1 MPa, toughness of 350 MJ m
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