ArticleAngewandte Chemie (International ed. in English)2026
The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
[1]Ferrocenophanes, which are single-atom bridged ansa-ferrocenes, have gained significant interest as monomers for ring-opening polymerization (ROP) reactions for the preparation of main-chain ferrocene-based metallopolymers. While all conceivable third and fourth row p-block elements are known as bridging atoms, boron remained the only second row p-block element to be incorporated into [1]ferrocenophanes, so far. Here, we describe the synthesis, isolation and full characterization of a carba[1]ferrocenophane, previously speculated to be unstable due to its high energy conformation. Single-crystal X-ray diffraction reveals the highest angular deflection from ferrocene's coplanarity so far (α = 36.7°, δ = 151.8°), which is reflected by its deep red color (λ
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