ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Electronic Modulation of Flexible Ether Oxygen-Based Covalent Organic Frameworks for Efficient Oxygen Reduction Reaction.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Ether oxygen-based covalent organic frameworks (EO-COFs) with intrinsic flexibility characteristics hold promise for applications in emerging electrochemical energy conversion technologies due to the adaptable pore microenvironments. However, achieving efficient oxygen reduction reaction (ORR) requires not only accessible pores but also facilitated charge transfer from the electrode to catalytically active sites within the extended framework and the simultaneous optimization of these two coupled processes remains challenging. Here, we synthesized two new EO-COFs and incorporated electron-withdrawing triazine units to enhance charge-transfer capability and modulate the electronic states, thereby improving their metal-free ORR activity. Moreover, the ether-oxygen moieties contribute to the formation of a more adaptive pore microenvironment and facilitate mass transport. Notably, the optimized THD-TOT-COF exhibits a high half-wave potential of 0.77 V and a turnover frequency value of 0.0021 s
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