Evidence map›Paper›PMID 42430495›Full record

ArticleScience advances2026

Oxidant-free Au(I)/Au(III) catalysis: Rational development of hemilabile proximity-guided N-heterocyclic carbenes.

Pengcheng Gao, Jihong Xu, Wenchao Chu, Yanhong Liu, Alejandro Cervantes-Reyes, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Dongju Zhang and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Science advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Pengcheng GaoDepartments of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY 10029, USA.ORCID 0000-0003-4266-0616
Jihong XuKey Lab of Colloid and Interface Chemistry, Ministry of Education, Institute of Theoretical Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
Wenchao ChuDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.
Yanhong LiuKey Lab of Colloid and Interface Chemistry, Ministry of Education, Institute of Theoretical Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.ORCID 0000-0002-2567-420X
Alejandro Cervantes-ReyesDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.ORCID 0000-0002-8443-3561
Elwira BiszDepartment of Chemistry, Opole University, 48 Oleska Street, Opole 45-052, Poland.ORCID 0000-0002-7070-2468
Błażej DziukDepartment of Chemistry, University of Science and Technology, Norwida 4/6, Wroclaw 50-373, Poland.
Roger LalancetteDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.
Roman SzostakDepartment of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland.ORCID 0000-0002-5436-7284
Dongju ZhangKey Lab of Colloid and Interface Chemistry, Ministry of Education, Institute of Theoretical Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.ORCID 0000-0002-6117-4958
Michal SzostakDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.ORCID 0000-0002-9650-9690

Funding

Catalytic Methods for Organic SynthesisR35GM133326 · NIGMS · RUTGERS THE STATE UNIV OF NJ NEWARK · PI Michal Szostak · 2019 to 2026
$2.7M
NIGMS NIH HHS R35 GM133326
6 · The paper itself

Abstract

In the past two decades, oxidant-free, ligand-enabled gold(I)/gold(III) [Au(I)/Au(III)] catalysis has become a potential complement to palladium(0)/palladium(II) [Pd(0)/Pd(II)] catalysis in diverse transformation, yet broadly general ligands for Au(I)/Au(III) catalysis remain lacking. Herein, we report a platform for ligand-enabled Au(I)/Au(III) catalysis through the rational development of hemilabile ImQun N-heterocyclic carbene (NHC) nitrogen (N),carbon (C) ligands (ImQun = imidazo[1,5-

Identifiers

PMID42430495
PMCPMC13353427

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.