Surface Electrochemistry of Au(111) in Acetonitrile Based Electrolytes: Formation of a Solvent Related Adsorbed Layer.

Greta P Grossman, Milena Martins, Alenka Krizan, Andrijana Marojevic, Jan Bitenc, Dusan Strmcnik, Marc T M Koper

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Article in The journal of physical chemistry letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Greta P GrossmanLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, 2333 CC Leiden, The Netherlands.ORCID 0009-0007-1669-7358

Milena MartinsNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.

Alenka KrizanNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.ORCID 0000-0002-5898-0553

Andrijana MarojevicNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.

Jan BitencNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.ORCID 0000-0002-0109-8121

Dusan StrmcnikNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.ORCID 0000-0002-3021-2771

Marc T M KoperLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, 2333 CC Leiden, The Netherlands.ORCID 0000-0001-6777-4594

Funding

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6 · The paper itself

Abstract

Fundamental understanding of the electrochemistry at metal/nonaqueous solvent interfaces is of importance both for improving organic solvent based electrochemical devices and also for generalizing theories of interfacial electrochemistry that were developed based on aqueous solvents. Herein we report electrochemical characterization of the Au(111)/acetonitrile (ACN) interface in verifiably clean conditions, in a potential region normally considered nonreactive or ideally polarizable. We demonstrate the formation of a solvent related adsorbed layer on the Au(111) surface upon contact with the electrolyte, which further undergoes oxidative and reductive transformations in subsequent cyclic voltammetry. The presence of this layer is further confirmed by

Identifiers

PMID42416990

DOI10.1021/acs.jpclett.6c01308

PMCPMC13403299

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