ArticleAdvanced materials (Deerfield Beach, Fla.)2026
2D In-Plane Molecular Superlattice Heterojunctions for High-Performance Ambipolar Electronics and Low-Dose X-Ray Sensing.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Two-dimensional in-plane molecular superlattice heterojunctions, where distinct semiconducting components are integrated laterally within a single crystalline plane, offer an ideal architecture for controlling charge separation and transport in optoelectronic devices. However, realizing such structures with molecular-level precision, long-range periodicity, and sharp interfaces in organic semiconductors remains a major challenge. Here, the first 2D organic heterojunction featuring long-range, in-plane donor-acceptor superlattice via cocrystal engineering is presented. By employing phase-separated molecular design for the donor (TIPS-PEN) and acceptor (PDI-FCN), strong in-plane cohesion is decoupled from out-of-plane steric repulsion, inducing a periodic -D-A-D- arrangement within the crystal plane. The resulting high-density, lattice-defined heterointerfaces facilitate exciton dissociation, directional charge transport, and efficient extraction. The ultrathin crystal enables effective gate-field control, yielding ambipolar OFETs with exceptional on/off ratios of 10
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