ArticleNature communications2026
Breaking the activity-selectivity dilemma in direct electrocatalytic hydrogenolysis of furfural into furanic biofuel.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Electrocatalytic hydrogenolysis of biomass-derived furfural usually encounters the disordered flow of electrons, particularly for the formation of 2-methylfuran with a complex four-electron transfer process. To address this, we develops an intermediates coverage-induced strategy through the mixed valences in copper clusters wrapped by carbonaceous matrix, which boosts the transfer of electrons toward 2-methylfuran with dual advantages in kinetics and thermodynamics. Experimental results indicate that the carbonaceous matrix create a furural-favorable environment for less adsorption of H
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