ReviewChemistry, an Asian journal2026
Recent Advances in Benzannulation Approaches to Aromatic Frameworks.
Review in Chemistry, an Asian journal, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Substituted arenes underpin pharmaceuticals, agrochemicals, and functional materials, yet conventional arene functionalization is often constrained by the substitution pattern of the starting ring. Benzannulation addresses this limitation by assembling aromatic cores from acyclic or nonaromatic precursors via metalcatalyzed cascades, pericyclic processes, radical cyclizations, and benzyne-based manifolds. This review highlights developments reported over the last 5 years and compares transition-metal-catalyzed and metal-free strategies in terms of bond-forming logic, regioselectivity, the functional-group tolerance, and mechanism. Design principles that enable step economy and improved sustainability are discussed, providing practical guidance for selecting and designing benzannulation routes to access complex substituted arenes.
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