ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Ordered Polar Topological Domains Enabling Giant Second-Harmonic Generation in Ferroelectric Nematic Liquid Crystals.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Developing high-performance nonlinear optical materials that simultaneously deliver large effective nonlinearity and device-level integrability remains a longstanding challenge. Ferroelectric nematic liquid crystals (FNLC) have emerged as a promising platform owing to their intrinsic non-centrosymmetry, theoretically predicted large second-order nonlinearity, and solution processability on diverse substrates. However, realizing strong second-harmonic generation (SHG) in FNLCs has been hindered by pronounced orientational disorder inherent to fluidic systems without lattice constraints. Here, this limitation is overcome through a surface-anchoring strategy that induces highly ordered polar topological structures within self-assembled FNLC droplets. The resulting architecture yields a giant effective SHG coefficient of 56.9 pm/V-an order of magnitude higher than previously reported FNLC systems-together with SHG efficiency surpassing that of benchmark LiNbO
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