ArticleAngewandte Chemie (International ed. in English)2026
Ring Strain Engineering of Cyclic Ethers for High-Performance Sodium Metal Batteries.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
1,3-dioxolane is a promising solvent for low-temperature batteries owing to its low freezing point and low viscosity. However, its tendency toward ring-opening polymerization leads to reduced ionic conductivity and deteriorated electrochemical stability. Here, we establish an electronic-geometric coupling design principle to regulate solvent stability in weak-weak electrolyte systems for sodium metal batteries. A dual-descriptor framework combining ring strain energy (RSE) and a sterically corrected electrostatic descriptor, defined by the lowest negative electrostatic potential normalized by molecular volume (ESP
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