ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
A Selectfluor-based Polonovski Rearrangement Leading to Novel Entities for Synthetic and Medicinal Applications.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The classical Polonovski reaction starting from N-oxides of tertiary amines and acid chlorides, or anhydrides, offers manifold synthetic options. This large preparative potential is now broadened by a novel, unusual version of the Polonovski reaction based on Selectfluor and carboxylic acids, through which new chemical entities for synthetic and medicinal applications become readily accessible under particularly mild conditions.
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