ArticleMagnetic resonance in chemistry : MRC2026
Interaction With Surface Spins as a Contribution to Nuclear Magnetic Relaxation of Liquids Adsorbed in Mesoporous Materials.
Article in Magnetic resonance in chemistry : MRC, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
NMR relaxation of liquids in the presence of solid interfaces, such as silica gel or porous glass, is affected by slowed-down and anisotropic molecular reorientations compared to the bulk, but also by the presence of spins as potential relaxation partners on or close to the surface. The latter contribution is predominantly considered as unpaired electrons in metal centers or surface radicals, but dipolar interactions with spin-bearing nuclei such as
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