ArticleScientific reports2026
Fabrication and DFT assisted investigation of novel Ru (III) imine complex for nickel corrosion inhibition and energy storage applications.
Article in Scientific reports, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Nickel metal is widely used in various applications, including surgical instruments, but its susceptibility to corrosion in acidic environments limits its applications and necessitates effective corrosion inhibition strategies. Herein, a novel Ru(III) tetra-dentate anil complex was synthesized and characterized, demonstrating exceptional performance as a corrosion inhibitor for nickel in 0.5 M sulfuric acid. The corrosion inhibition performance was evaluated using Tafel plots and electrochemical impedance spectroscopy, while the electronic properties and adsorption behavior were investigated using DFT calculations and Monte Carlo simulations. The complex also exhibits promising charge-discharge characteristics, suggesting its potential in energy storage applications. The RuL complex significantly reduced the corrosion current density, achieving a maximum inhibition efficiency of 99.4% at an optimal dosage of 1 × 10
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