ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Molecularly Engineered Self-Healing Scaffold With Customized Dynamic Bonds Enable Stable and Scalable Flexible Perovskite Solar Cells and Modules.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Organometallic halide perovskites hold great promise as materials for high-performance flexible perovskite solar cells (f-PSCs). However, achieving uniform, highly crystalline, and mechanically robust perovskite films remains a critical challenge for f-PSCs. Here, a tandem dynamic bond-based monomer (ADM) was incorporated into a perovskite film, where it cross-links in situ to control nucleation and crystallization. This enables multi-modal passivation via Lewis-base coordination and hydrogen bonding between ADM and the perovskite lattice. The tandem dynamic bonds within the cross-linked network, preferentially residing at grain boundaries, endow the flexible perovskite films with an instantaneous self-curing capability under mild treating conditions (40°C for 30 min). As a result, champion devices deliver a power conversion efficiency (PCE) of 27.12% (certified 26.80%) for small-area rigid PSCs and 20.00% for a flexible minimodule (10.24 cm
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