The Exploration of TPhos as a Monodentate P-Ligand for Palladium-Catalyzed Regioselective Hydrothiocarbonylation of Styrenes under Neutral Conditions.

Chang-Sheng Kuai, Wen Che, Shou-Fei Zhu, Xiao-Feng Wu

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Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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4 · The record

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5 · Who and what money

Authors and funding

4 authors.

Chang-Sheng KuaiDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 China.

Wen CheAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center of New Organic Matters, State Key Laboratory and Institute of Elemento Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.

Shou-Fei ZhuAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center of New Organic Matters, State Key Laboratory and Institute of Elemento Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.ORCID 0000-0002-6055-3139

Xiao-Feng WuDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 China.ORCID 0000-0001-6622-3328

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A palladium-catalyzed nonacidic hydrothiocarbonylation of styrenes with CO and thiols has been developed. Utilizing a cyclopropane-based monophosphine ligand (TPhos), this protocol enables the efficient and branched-selective synthesis of alkyl thioesters under mild and neutral conditions with broad substrate scope and excellent functional group tolerance.

Identifiers

PMID42373563

DOI10.1021/acs.orglett.6c02424

PMCPMC13366686

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