Evidence map›Paper›PMID 42368435›Full record

ArticleChemical science2026

Covalently linked ferrocene-polyoxometalate dyads for light-induced radical generation.

Sebastian Knoll, Heiner Schmidt, Kevin Sowa, Benjamin Dietzek-Ivanšić, Celina Titze, Stephan Kupfer, Linda Zedler, Carsten Streb

Abstract read
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Sebastian KnollInstitute of Inorganic Chemistry I, Ulm University Albert-Einstein-Allee 11 89081 Ulm Germany.
Heiner SchmidtInstitute of Physical Chemistry, Friedrich Schiller University Jena Helmholtzweg 4 07743 Jena Germany stephan.kupfer@uni-jena.de.
Kevin SowaDepartment of Chemistry, Johannes Gutenberg University Mainz Duesbergweg 10-14 55128 Mainz Germany carsten.streb@uni-mainz.de.
Benjamin Dietzek-IvanšićInstitute of Physical Chemistry, Friedrich Schiller University Jena Helmholtzweg 4 07743 Jena Germany stephan.kupfer@uni-jena.de.ORCID https://orcid.org/0000-0002-2842-3537
Celina TitzeInstitute of Physical Chemistry, Friedrich Schiller University Jena Helmholtzweg 4 07743 Jena Germany stephan.kupfer@uni-jena.de.ORCID https://orcid.org/0009-0005-4292-2542
Stephan KupferInstitute of Physical Chemistry, Friedrich Schiller University Jena Helmholtzweg 4 07743 Jena Germany stephan.kupfer@uni-jena.de.ORCID https://orcid.org/0000-0002-6428-7528
Linda ZedlerInstitute of Physical Chemistry, Friedrich Schiller University Jena Helmholtzweg 4 07743 Jena Germany stephan.kupfer@uni-jena.de.
Carsten StrebInstitute of Inorganic Chemistry I, Ulm University Albert-Einstein-Allee 11 89081 Ulm Germany.ORCID https://orcid.org/0000-0002-5846-1905

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The design of covalently linked photoactive donor-acceptor dyads offers major opportunities for photocatalysis and solar energy conversion. Here, we report a noble metal-free dyad obtained by covalent anchoring of a ferrocene moiety to a Dawson-type polyoxotungstate. The resulting dyad shows visible light photoinduced charge-separation and electron transfer from the ferrocene to the polyoxometalate. The separated charges can be used for the photoinduced, oxidative and reductive activation of organic peroxides to generate oxygen-based radicals. Structural and mechanistic studies using

Identifiers

PMID42368435
PMCPMC13307311

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.