ArticlePolymers2026
Fracture Mode Transition and Energy Dissipation of Brittle Coal Under Confinement Induced by a Flexible Polyurea Coating.
Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Brittle geomaterials such as coal and rock are prone to unstable failure under high stress and dynamic disturbances, where rapid release of stored elastic strain energy can trigger dynamic disasters. Polyurea, a high-strength and high-ductility elastomer, can form a continuous flexible coating on the surface of coal/rock to regulate their deformation-fracture behavior. Here, uniaxial compression tests were performed on coal specimens coated with polyurea layers of different thicknesses (0-1.25 mm). Acoustic emission (AE) and digital image correlation (DIC) were jointly employed to characterize macroscopic deformation, microcrack evolution, fracture-mode transition, and energy partitioning. The results show that polyurea provides passive lateral confinement that suppresses lateral expansion and shifts macroscopic failure from brittle splitting to progressive ductile damage. AE-based AF-RA analysis indicates that thicker coatings increase the normal stress and shear resistance along potential fracture planes, promoting a microfracture transition from shear-dominated to tension-dominated cracking. Energy analysis demonstrates that the coating enhances pre-peak energy dissipation via coordinated deformation with the coal, while thicker coatings (≥1.00 mm) exhibit pronounced post-peak elastic tensile deformation to absorb and buffer fracture-released energy, impeding the instantaneous energy release typical of bare coal. Moreover, the elastic energy index shows that polyurea markedly reduces impact tendency, with an appropriate thickness stabilizing specimens from strong to weak/non-impact propensity. These findings clarify the coupled confinement-fracture-energy regulation mechanisms of polyurea coatings and provide quantitative guidance for coating-thickness design to mitigate dynamic failure hazards in brittle materials.
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