ArticlePolymers2026
Toughening, Reinforcing, and Reprocessing of Epoxy Resin with Hyperbranched Polymer Containing Disulfide and Imine Dual Dynamic Covalent Bonds.
Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Epoxy resins are extensively utilized in various fields for their excellent comprehensive performance. However, the inherent brittleness and lack of reprocessing ability greatly limit their sustainability. In order to obtain reprocess ability in epoxy resin with superior mechanical properties and thermal stability, a curing agent (VA) and a hyperbranched epoxy toughening agent (HVT) containing disulfide and imine bonds have been synthesized from vanillin. Owing to the distinctive topological structure and abundant epoxy terminal groups of HVT, the modified epoxy resin (5HVT/E51/VA) exhibits high toughness, enhanced mechanical strength, and favorable thermal stability. When compared to the properties of the unmodified resin, the impact and flexural strength of 5HVT/E51/VA are increased by 55.32% and 71.63%, respectively. Its glass transition temperature (
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