MXene-Based Electrodes for Flexible Supercapacitors: From Material Synthesis to Device Integration.

With the rapid advancement of portable wearable electronics, flexible supercapacitors have ushered in new development opportunities. In recent years, MXene and its composites have demonstrated potential as advanced supercapacitor electrode materials due to their outstanding theoretical capacitance, specific surface area, conductivity, hydrophilicity, and mechanical flexibility. This review traces the development of MXene and summarizes common synthesis strategies, with a focus on the effects of different preparation methods on its structure and properties. Departing from previously reported work, this review draws from the practical requirements of flexible supercapacitors to conduct an in-depth analysis of the key factors influencing the charge storage, rate capability, cycling life, and mechanical flexibility of the devices. It summarizes common design strategies for MXene composites currently used to enhance device performance. Additionally, this study analyzes key challenges facing MXene-based electrode materials, including issues such as self-stacking of layers, insufficient oxidation stability, limited energy density, and structural degradation under complex deformation conditions. Mitigation strategies are summarized, including optimizing synthesis methods and constructing composite systems integrating carbon materials, conducting polymers, and transition metal compounds. Finally, future research directions for MXene in flexible energy storage are explored, emphasizing the need to achieve a balance between performance and manufacturability through synergistic regulation at structural design, interfacial engineering, and device levels. This review aims to provide theoretical guidance for the development of practical MXene-based wearable energy storage devices.