ReviewMaterials (Basel, Switzerland)2026
The Phenomenology of the Chromic Response in Transition-Metal Oxides.
Review in Materials (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
Chromic materials exhibiting reversible changes in optical properties under external stimuli represent an important class of smart materials with applications in smart windows, sensors, and optoelectronic devices. Transition-metal oxides (TMOs) provide a versatile platform for chromic functionality due to their coupled structural, electronic, and optical properties. In this review, the chromic response of selected TMO thin films is analyzed using both microscopic and phenomenological approaches. The microscopic description is based on many-body theory, including Green's function methods and correlation effects, while the macroscopic optical response is described using Drude-Lorentz and Tauc-Lorentz models within the effective medium approximation. Chromic behavior in TMOs is shown to originate from two principal mechanisms: (i) electronic and structural reconstruction driven by Peierls-Mott metal-insulator phase transitions, leading to thermochromism (notably in VO
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