ArticleMaterials (Basel, Switzerland)2026
Ether-Functionalized Polybenzimidazole Composite Separators for Enhanced Performance and Sustainable Lithium-Ion Batteries.
Article in Materials (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Polybenzimidazole (PBI) is a promising separator for lithium-ion batteries (LIBs) owing to its excellent thermal/chemical stability and mechanical strength, but its application is limited by poor solubility and processability. Herein, a novel ether-functionalized PBI was synthesized, and three-layer composite separators (PBIPHPE) were fabricated by electrospinning PBI/PVDF-HFP blends onto polyethylene (PE) substrate. The PBIPHPE separator exhibits high porosity (73.1%), superior electrolyte uptake (211.2%), and excellent ionic conductivity (1.125 mS/cm), with no dimensional change after thermal treatment at 150 °C for 0.5 h. Lithium-ion batteries assembled with PBIPHPE deliver an initial specific capacity of 157.7 mAh/g, retain 86.0% capacity after 400 cycles at 2 C, and show only 15.7% capacity decay from 0.2 C to 5 C. Molecular dynamics simulations of the composite separator-electrolyte system were performed to reveal Li
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