ArticleInternational journal of molecular sciences2026
Modulation of Triplet-State Reactivity and Enhanced Singlet Oxygen Generation in Tricyclic Thiopurine Analogues.
Article in International journal of molecular sciences, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Thiopurines are efficient triplet-state photosensitisers; however, the practical application of canonical derivatives such as 6-thioguanine (6TG) and 6-thioguanosine (6TGuo) is limited by competing deactivation pathways that reduce the fraction of triplet states available for productive interaction with molecular oxygen. In this work, we investigated how structural modification of the thiopurine scaffold through introducing of an additional five-membered etheno ring affects triplet-state energetics, deactivation pathways, and singlet oxygen sensitisation. The photophysical properties of four tricyclic thiopurine analogues-9-thio-1,N
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