Topology Switching in Polymetallic Fragments Governed by Metal Encapsulation.

Niklas Geue, Kim Greis, Hari R Newnham, Grigore A Timco, Richard E P Winpenny, Perdita E Barran

Abstract read

In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Niklas GeueInstitute of Chemistry and Biochemistry, Freie Universität Berlin, Altensteinstraße 23a, Berlin 14195, Germany.ORCID 0000-0002-5216-8353

Kim GreisLaboratory for Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, Zurich CH-8093, Switzerland.ORCID 0000-0002-9107-2282

Hari R NewnhamMichael Barber Centre for Collaborative Mass Spectrometry, Manchester Institute of Biotechnology, Department of Chemistry, The University of Manchester, 131 Princess Street, Manchester M1 7DN, U.K.ORCID 0000-0002-5707-8103

Grigore A TimcoDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0003-0966-0315

Richard E P WinpennyDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0002-7101-3963

Perdita E BarranMichael Barber Centre for Collaborative Mass Spectrometry, Manchester Institute of Biotechnology, Department of Chemistry, The University of Manchester, 131 Princess Street, Manchester M1 7DN, U.K.ORCID 0000-0002-7720-586X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metallosupramolecular assemblies are promising platforms for selective extraction, catalysis, and molecular recognition, yet their solution-phase synthesis often relies on complex self-assembly pathways that can be difficult to control. Here, using ion mobility mass spectrometry supported by density functional theory calculations, we introduce a gas-phase approach for directing topology in polymetallic complexes based on the encapsulation of coordination metal cations within a homometallic {Cr

Identifiers

PMID42347689

DOI10.1021/jacs.6c06300

PMCPMC13352637

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.