ArticleToxics2026
Spectral Characteristics of Dissolved Organic Matter and Their Associations with Heavy Metal Distribution in Multi-Media of a Typical Frozen Eutrophic Lake.
Article in Toxics, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
9 authors.
Funding
Abstract
In cold arid regions, the relationships between dissolved organic matter (DOM) characteristics and heavy metal distributions across ice, water, and sediment interfaces remain insufficiently resolved. This study characterized DOM spectral features and examined their associations with measured metal distributions in a typical frozen eutrophic lake using excitation-emission matrices coupled with parallel factor analysis (EEMs-PARAFAC), ultraviolet-visible absorption spectroscopy (UV-Vis), and Fourier-transform infrared spectroscopy (FTIR). Protein-like substances dominated ice DOM, whereas water and sediment-derived DOM contained more humified fluorescent components. Fluorescence indices confirmed a primarily biological origin across all media, with ice showing the highest autochthonous microbial contribution (BIX = 1.23) but the lowest humification (HIX = 0.26), suggesting a greater contribution of recently produced protein-like fluorescent DOM in the ice samples. Water DOM showed the highest average HIX (1.88), followed by sediment-derived DOM (0.61) and ice DOM (0.26). The measured hydrochemical conditions, including weak alkalinity, elevated total dissolved solids (TDS), and locally low dissolved oxygen, provide environmental context for differences in metal distributions. Exploratory Spearman analysis at 17 matched water stations identified the strongest DOM-metal associations for HIX-As (rho = 0.474,
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