Evidence map›Paper›PMID 42344311›Full record

ArticlePolyhedron2022

Zinc-based cyclens containing pyridine and cross-bridges: X-ray and DFT structures, Lewis acidity, gas-phase acidity, and p

Douglas P Linder, Blake Vinson, Rylee Parks, Audra Crisp, Ashtyn G McAdoo, Jonathan P Ebel, Tuyet Hoang, Houston Smith, Allen G Oliver, Timothy J Hubin

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Polyhedron, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Douglas P LinderDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Blake VinsonDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Rylee ParksDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Audra CrispDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Ashtyn G McAdooDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Jonathan P EbelDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Tuyet HoangDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Houston SmithDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.
Allen G OliverDepartment of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN, 46556, United States.
Timothy J HubinDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, United States.

Funding

Proteomics CoreP20GM103447 · NIGMS · UNIVERSITY OF OKLAHOMA HLTH SCIENCES CTR · PI Mark L Lang · 2012 to 2026
$60.2M
NIGMS NIH HHS P20 GM103447
6 · The paper itself

Abstract

It is well known that catalytic centers containing the zinc(II) ion can act as both Lewis and Bronsted-Lowry acids. In addition to coordination number, the Zn coordination geometry can also strongly impact the acidity of the active site, no matter what measure of acidity is considered. Herein, we report the first pentacoordinate, zinc-ammonia complex containing a pyridine based tetraazamacrocycle, [(pyclen)Zn(NH

Indexed as

CyclenDensity functional theoryLewis acidX-ray diffractionZinc azamacrocycle

Identifiers

PMID42344311
PMCPMC13289715

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.