ArticleChemical science2026
Increasing connectivity through self-complementarity enables permanent porosity in a halogen-bonded organic framework.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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15 authors.
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Abstract
Halogen bonding has emerged as an intuitive and programmable handle for constructing ordered, low-density molecular solids. However, its ability to support permanent porosity has not been realized. Here, we report a self-complementary strategy that surpasses this long-standing limitation, delivering the first rigorously characterized permanently porous halogen-bonded organic framework (XOF). A threefold-symmetric, 2-iodooxazole-terminated tecton spontaneously assembles into a low-density, crystalline network that remains intact upon complete solvent removal. Permanent porosity is confirmed by N
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