ArticleScientific reports2026
Highly selective removal of cationic dye using a novel synthesized polyacrylic polyacrylamide phosphate (PAA@PAm@P) hydrogel.
Article in Scientific reports, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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11 authors.
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Abstract
In this study, a novel phosphate-functionalized hydrogel adsorbent, poly(acrylic acid-g-polyacrylamide) phosphate (PAA@PAm@P), was successfully synthesized for considerable adsorption of methylene blue (MB)-dye from aquatic solutions. The base hydrogel, poly(acrylic acid-g-polyacrylamide) (PAA@PAm), was prepared via free-radical copolymerization of acrylic acid and acrylamide, followed by mechanical homogenization to obtain hydrogel particles. Surface modification was subsequently achieved through phosphorylation using trisodium phosphate at 180 °C for 4.0 h, yielding the functionalized micron-sized PAA@PAm@P hydrogel. The fabricated materials were characterized using different analytical techniques, such as SEM, FTIR, TGA, and EDS, to confirm successful structural modification and functional groups incorporation. Batch adsorption experiments were conducted to investigate the influence of operational parameters including contact time, adsorbent dose, initial pH, initial MB-dye concentrations, NaCl concentrations, and temperature. The modified micron-sized PAA@PAm@P hydrogel exhibited rapid adsorption kinetics, reaching equilibrium within 15.0 min, which is twice as fast as the unmodified PAA@PAm (30.0 min). The material also demonstrated exceptional swelling behavior with a maximum swelling ratio of 5590% within 3 min, significantly higher than that of PAA@PAm (1712% after 7.0 min). Experimental results indicated that kinetic data were best described by pseudo-second-order (R
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