ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Competitive Solvation-Driven Interface Stabilization for Protic Deep Eutectic Solid Electrolyte in Sodium-Metal Batteries.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Solid-state sodium batteries (SSSBs) are promising for safe and high-energy storage, while their development is hindered by the low ionic conductivity of solid electrolytes and severe interfacial side reactions, especially when protic deep eutectic electrolytes (DEEs) are employed to enhance conductivity. The active hydrogen in typical DEEs (e.g., N-methylacetamide, NMA) readily reacts with the sodium metal negative electrode, leading to rapid performance decay. Herein, we propose a solvation reconstruction strategy to address this issue by incorporating polar carbonate ester into a composite solid electrolyte (CSE) based on NaTFSI-NMA DEE. Carbonate ester molecules preferentially enter the solvation structure of Na
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