ArticleAngewandte Chemie (International ed. in English)2026
Non-Superacid-Catalyzed Preparation of Anion Exchange Membranes for High-Performance Water Electrolyzers.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Recent advances in anion exchange membrane water electrolyzers (AEMWEs) have been primarily driven by anion exchange membranes (AEMs) prepared via superacid-catalyzed polymerization. However, the reliance on highly corrosive trifluoromethanesulfonic acid (TFSA; pKa = -14.7) employed both as catalyst and solvent poses significant safety, handling, and scalability challenges for industrial AEM manufacturing. Herein, we report a nonsuperacid polymerization strategy for AEMs, utilizing methanesulfonic acid (MSA; pKa = -1.9) to catalyze the Friedel-Crafts alkylation between electrophilic aminobenzaldehyde and electron-rich dibenzo-18-crown-6. Crown ether incorporation expands interchain spacing, thereby facilitating the formation of continuous hydrophilic ion-conducting channels. Furthermore, complexation of potassium ions with crown ether moieties weakens the electrostatic interaction between K
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