Breathing Bimetallic MOF Confined Polyoxometalates for Hydration Layer Loosening and Electronic Redistribution Toward Efficient Nitrate Electroreduction and Zn-Nitrate Batteries.

Qiushuang Jiang, Xinming Wang, Chao Wang, Shengji Tian, Nan Zhao, Haijun Pang, Chade Lv, Zhipeng Yu, Hong-Ying Zang

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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5 · Who and what money

Authors and funding

9 authors.

Qiushuang JiangSchool of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin, P. R. China.

Xinming WangSchool of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin, P. R. China.ORCID https://orcid.org/0000-0002-5418-9182

Chao WangCollege of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, P. R. China.

Shengji TianMIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, P. R. China.

Nan ZhaoSchool of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin, P. R. China.

Haijun PangSchool of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin, P. R. China.ORCID https://orcid.org/0000-0002-0405-8352

Chade LvMIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, P. R. China.ORCID https://orcid.org/0000-0002-0964-1037

Zhipeng YuClean Energy Cluster, International Iberian Nanotechnology Laboratory (INL), Braga, Portugal.ORCID https://orcid.org/0000-0002-3208-649X

Hong-Ying ZangKey Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, P. R. China.ORCID https://orcid.org/0000-0002-8148-0303

Funding

Heilongjiang Provincial Natural Science Foundation LH2024B015Heilongjiang Provincial Science and Technology Innovation Base Award Program JD25A023National Science Foundation of China 22171059National Science Foundation of China 22322102National Science Foundation of China 32541097Shandong Provincial Natural Science Foundation ZR2022MB096

6 · The paper itself

Abstract

The traditional Haber-Bosch method suffers from harsh conditions and high energy consumption, while electrocatalytic nitrate reduction to ammonia (ENRA) is a green route for ammonia synthesis and can serve as a cathode reaction for Zn-nitrate batteries. Its development is limited by sluggish intermediate hydrogenation and severe hydrogen evolution reaction (HER). Herein, we develop topology-engineered isomeric polyoxometalate (POM)-confined bimetallic metal-organic framework (MOF) electrocatalysts (NH

Indexed as

breathing effectelectrocatalytic nitrate reductionpolyoxometalate‐based metal‐organic frameworksproton transferZn−nitrate battery

Identifiers

PMID42329178

DOI10.1002/anie.6487495

PMCPMC13502558

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.