Complete Linker Desymmetrization Enabled Construction of an eft-Topological Zr(IV)-MOF Comprising Two Types of Hexazirconium Nodes for Ammonia Capture.

Pengfu Gao, Jingjing Zhang, Yuan Geng, Chao Jiang, Yong Cui, Wei Gong

Abstract read

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Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

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1 citing paper in PubMed.

Complete Linker Desymmetrization Enabled Construction of an eft-Topological Zr(IV)-MOF Comprising Two Types of Hexazirconium Nodes for Ammonia Capture.Angewandte Chemie (International ed. in English) · 2026
Article

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Authors and funding

6 authors.

Pengfu GaoState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.

Jingjing ZhangState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.

Yuan GengState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.

Chao JiangState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.

Yong CuiState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.ORCID https://orcid.org/0000-0003-1977-0470

Wei GongState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China.ORCID https://orcid.org/0000-0002-1458-054X

Funding

National Key R&D Program of China 2023YFA1507601National Natural Science Foundation of China 22301176National Natural Science Foundation of China 22522108National Natural Science Foundation of China 52373213

6 · The paper itself

Abstract

Rational design and serendipitous discovery constitute the two wheels of molecular science. Despite the fruitful achievements of constructing metal-organic frameworks from highly symmetric linkers under the guidance of reticular chemistry principles, the formulation of synthetic principles with unsymmetric organic linkers, while fundamentally important for targeting unexpected structures and functions, has been underdeveloped. Herein, we achieved a Zr(IV)-based MOF (SJTU-24) with a computationally modelled trinodal (3,4,8)-connected eft topology where two types of Zr

Indexed as

ammonia captureeft topologylinker desymmetrizationmetal‐organic frameworkreticular chemistry

Identifiers

PMID42323798

DOI10.1002/anie.9211185

PMCPMC13502638

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