ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Amphiphilic Bonding Intercalation Reshapes Active Sites and Interlayer Microenvironment for Selective and Stable Seawater Oxidation.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Direct seawater electrolysis is severely constrained by the activity-durability trade-off and chloride-induced corrosion. Herein, we design corrosion-resistant, highly selective layered double hydroxide (LDH) catalysts by transitioning interlayer bonding from weak electrostatic attraction to strong coordination. Amphiphilic dodecylbenzenesulfonate (SDBS) coordinates with Fe active centers, forming robust Fe─O─S bonds that establish a securely locked microenvironment. Density functional theory reveals this coordination upshifts the Fe d-band center and enhances Fe─O covalency, lowering the thermodynamic oxygen evolution barrier. Simultaneously, molecular dynamics simulations show that hydrophobic alkyl tails reorganize the interfacial hydrogen-bond network. This creates a kinetic barrier against chloride, enabling high hydroxide-to-chloride diffusion selectivity (D
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