ArticleJournal of the American Chemical Society2026
Initiating Photocontrolled Atom Transfer Radical Polymerization from a Redox-Activated Functional Group.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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3 authors.
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Abstract
Initiating controlled radical polymerizations directly from common functional groups is desirable for synthesizing advanced polymer architectures, such as surface grafts and polymer conjugates. Previously, photocontrolled atom transfer radical polymerization (ATRP) has been performed with alkyl halide initiators, limiting its utility in these advanced polymer applications. In this study, we demonstrate the initiation of photo-ATRP directly from the α-carbon of primary amines. We employ an iridium photocatalyst to trigger radical deamination of redox-activated primary amines, initiating controlled radical polymerization in the presence of an exogenous bromide source under visible light irradiation. The resulting polymers have narrow molar mass distributions (
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