ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The controlled generation of the unsubstituted ("naked") cyclopropyl radical remains a long-standing challenge due to the difficulty of finding effective precursors and reaction conditions that are easy to implement, as well as its high reactivity. Here we report an oxidative photoredox strategy that enables direct access to the cyclopropyl radical from the easily prepared cyclopropyl Martin silicate. In contrast to prevailing reductive approaches (NHP esters, halides), this method eliminates sacrificial metal reductants and enables two distinct transformations: (i) Giese-type additions to electron-deficient alkenes and diazenes, and (ii) dual Ni/photoredox C(sp
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