ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Spider Silk-Like Nanodomain Spacings Enable Mechanically Robust and Healable Elastomers with Record-High Puncture Resistance.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Spider silk is an exceptionally strong, extensible, and tough natural material, the outstanding mechanical properties of which arise from β-sheet nanocrystalline protein domains with an average lattice spacing of approximately 10 nm. Herein, inspired by the microstructure of spider silk, a mechanically robust, healable, and reprocessable fluorinated supramolecular poly(urethane-urea) (F-SPUU) elastomer with record-high puncture energy (889 mJ), is reported. The high-performance stems from the cross-linking of polytetrahydrofuran chains with in situ-formed phase-separated nanodomains (lattice spacing: 10.02 nm), closely resembling that observed in spider silk. These nanodomains consist of dynamic hydrogen bonded arrays and fluorinated phenol-carbamate bonds. They not only serve as rigid nanofillers that reinforce elastomers, but deform and disintegrate under external forces, dissipating energy to improve puncture resistance and damage tolerance, while endowing elastomers with self-healability and reprocessability due to their reversibility. As a result, the F-SPUU elastomer exhibits high tensile strength (39.6 MPa), superior fracture energy (90.8 kJ m
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