Metal-Dependent Kinetic Control in Cationic-Anionic Synchronous Ring-Opening Polymerization.

Jie Xuan, Wenli Wang, Yunqing Zhu, Jianzhong Du

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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2 · The registry

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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5 · Who and what money

Authors and funding

4 authors.

Jie XuanDepartment of Polymeric Materials, Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai, China.ORCID https://orcid.org/0009-0005-0836-3169

Wenli WangDepartment of Polymeric Materials, Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai, China.ORCID https://orcid.org/0000-0002-2654-7173

Yunqing ZhuDepartment of Polymeric Materials, Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai, China.ORCID https://orcid.org/0000-0002-2557-003X

Jianzhong DuDepartment of Polymeric Materials, Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai, China.ORCID https://orcid.org/0000-0003-1889-5669

Funding

Fundamental Research Funds for the Central UniversitiesInnovation Program of Shanghai Municipal Education Commission 2023ZKZD28National Natural Science Foundation of China 21925505National Natural Science Foundation of China 22335005National Natural Science Foundation of China 22401216National Natural Science Foundation of China 22575176Science and Technology Commission of Shanghai Municipality 25JD1401000Tongcheng Youth Research and Development Fund CPCIF-RA-0104

6 · The paper itself

Abstract

Synchronous polymerization that combines mechanistically orthogonal pathways within a single catalytic system offers an attractive route to well-defined block copolymers, yet remains challenging because it requires balancing electronically opposing reactions. Here, we systematically investigate how p-block metal chlorides regulate cationic-anionic synchronous ring-opening polymerization (CAP) of 2-oxazolines and cyclic esters. By comparing GaCl

Indexed as

2‐oxazolinescyclic esterskineticsp‐block metalsring‐opening polymerization

Identifiers

PMID42313896

DOI10.1002/anie.5992061

PMCPMC13480723

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.