ArticleInorganic chemistry2026
Oxygenated N-Confused Porphyrins: Structural Elucidation and Distinct Vanadium(IV) Coordination Motifs.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
N-Confused porphyrinoids exhibit unusual structural and electronic properties arising from pyrrole inversion, yet the controlled oxygenation of these macrocycles remains underdeveloped because competing pathways often generate complex mixtures. Here, we identify a stepwise oxygenation sequence associated with vanadium metalation of an N-confused porphyrin (NCP) framework, providing access to structurally defined oxygenated NCP derivatives and their vanadium complexes. The lactam-containing NCP 3-oxo-
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