ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Conjugated Polymer-Halogenated Alkane Synergy: 19.37% Efficiency in Binary Organic Solar Cells.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The morphological instability of the active layers remains a critical bottleneck limiting the photovoltaic performance and long-tern operational stability of organic solar cells (OSCs). In this work, the synergistic mechanism of the conjugated polymer PM6 and halogenated alkane additive 1,8-diiodooctane (DIO) was systematically investigated to understand the effect on the microstructure and photovoltaic performances of the D18:BTP-BO-4F-based OSCs active layer. The results demonstrate that the co-introduction of PM6 and DIO effectively refines the phase separation morphology, modulates donor-acceptor molecular aggregation, and promotes favorable nanoscale domain connectivity. This synergistic approach not only enhances the carrier transport and extraction but also significantly inhibits both monomolecular and bimolecular recombination losses. Consequently, the power conversion efficiency of the binary OSCs increases from 16.68% to 19.37%, accompanied by an open circuit voltage of 0.882 V, a short-circuit current density of 28.45 mA cm
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